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Published 19:06 13 May 2018 BST
Updated 19:17 13 May 2018 BST
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Ali opted for a full-length metallic silver gown and a simple black clutch. She kept hair and make-up fairly classic and accessories to a minimum too.
Dec wasn't joined by his side-kick, Ant McPartlin - who is still recovering following his arrest for drink-driving in March.
Still, the hosting duo are up for the likes of Best Entertainment Programme - for both Saturday Night Takeaway and Britain's Got Talent. Sue Perkins is hosting the ceremony.
Last month, a source close to the Dec, 42, and Ali, 39, said the pair were “delighted to be expecting - especially since they have been trying for some time”.
"They have both always wanted a family but worried that it might not happen for them," the same source added in conversation with The Sun.
"They have been keeping the pregnancy a closely guarded secret, but now that Ali is safely over 12 weeks, they are starting to let people know".
Dec and Ali were together for 18 months before marrying in August 2015.
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