Absolutely heartbreaking.

Jennifer Aniston and Brad Pitt's relationship is one that just can't die. While many celebrity couples have come and gone over the years, for some reason people hold out hope that they will somehow rekindle their love for each other. Jennifer split from her husband Brad in 2005. She was filming the last series of Friends and he was filming Mr and Mrs Smith - where he eventually met his next wife. At the wrap party for Friends, things seemed rocky enough between the pair as Brad didn't attend any of the events. They put it down to work commitments but only a few months later they announced their split. However, when Jennifer was still filming Friends, just before Brad went off to film Mr and Mrs Smith, the actress met Angelia Jolie in a car park. The car park was actually the one on the Friends set, and knowing her then-husband would soon be filming a movie with Angelina, Jen went over to talk to her. In an uprooted article by Vanity Fair, Jennifer spoke about the one and only time she met Angelina. "I pulled over and introduced myself," Jen began. "I said, 'Brad is so excited about working with you. I hope you guys have a really good time'." And that was it.